m-Chloroperbenzoic acid → 3-methylsulfinyl-N'-sulfamoylpropanimidamide

HRID 2413345노트

반응식

HRID 2413345 반응식
ClC1C=CC=C(C(OO)=[O:9])C=1.[S:12]([NH:16][C:17](=[NH:22])[CH2:18][CH2:19][S:20][CH3:21])(=[O:15])(=[O:14])[NH2:13]>C(Cl)(Cl)Cl.CO>[S:12]([NH:16][C:17](=[NH:22])[CH2:18][CH2:19][S:20]([CH3:21])=[O:9])(=[O:14])(=[O:15])[NH2:13]

참가 물질

5

반응물 2

HCID 70297m-Chloroperbenzoic acidHCID 178503794HCID 178503794, 화합물

생성물 1

HCID 1785046403-methylsulfinyl-N'-sulfamoylpropanimidamide

시약·촉매·용매 2

HCID 887Methanol용매HCID 6212Chloroform용매

실험 절차

A solution of commercial 80% pure m-chloroperbenzoic acid (5.4 g, 25 mmol) in chloroform (40 ml) was added dropwise to a solution of N-sulfamyl-3-(methylthio)propionamidine (4.94 g, 25 mmol) in methanol (50 ml) at room temperature. After stirring for two hours, the product was collected by filtration, analytically pure, to give 4.44 g, mp 141°-144°.

후처리

  1. filtrationthe product was collected by filtration
  2. customanalytically pure, to give 4.44 g, mp 141°-144°

출처 및 근거

ORD 기록
ord-461e854f44064aca83215e2c4ef6b828
출처 데이터셋
uspto-grants-1985_01
특허 번호
US04496737

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