Hydrochloric Acid → 3-Phenoxybenzaldehyde

HRID 2420051노트

반응식

HRID 2420051 반응식
[O:1]([C:8]1[CH:9]=[C:10]([CH:13]=[CH:14][CH:15]=1)[CH2:11]Cl)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[O:16](C1C=C(C=CC=1)C(Cl)Cl)C1C=CC=CC=1.C1N2CN3CN(C2)CN1C3.Cl>C(O)C.C(O)(=O)C>[O:1]([C:8]1[CH:9]=[C:10]([CH:13]=[CH:14][CH:15]=1)[CH:11]=[O:16])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

참가 물질

7

반응물 4

HCID 313Hydrochloric AcidHCID 4101HexamethylenetetramineHCID 932913-Phenoxybenzyl chlorideHCID 1046311-(Dichloromethyl)-3-phenoxybenzene

생성물 1

HCID 382843-Phenoxybenzaldehyde

시약·촉매·용매 2

HCID 176Acetic Acid용매HCID 702Ethanol용매

실험 절차

A process according to claim 1, wherein the mixture of m-phenoxybenzyl chloride (II) and m-phenoxybenzal chloride (III) (X = chlorine) is reacted with 1 to 2 molar equivalent of hexamethylenetetramine in hot aqueous ethanol or hot aqueous acetic acid and hydrolyzing the mixture with dilute hydrochloric acid to yield m-phenoxybenzaldehyde (I).

출처 및 근거

ORD 기록
ord-0f655a5e55a5424fb394002feb0622e1
출처 데이터셋
uspto-grants-1978_08
특허 번호
US04108904

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