(Phenylthio)acetic acid → (Phenylthio)acetyl chloride

HRID 246816

반응식

HRID 246816 반응식
[C:1]1([S:7][CH2:8][C:9]([OH:11])=O)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C(Cl)(=O)C([Cl:15])=O>C1(C)C=CC=CC=1>[C:1]1([S:7][CH2:8][C:9]([Cl:15])=[O:11])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

참가 물질

4

반응물 2

HCID 59541(Phenylthio)acetic acidHCID 65578Oxalyl chloride

생성물 1

HCID 4063350(Phenylthio)acetyl chloride

시약·촉매·용매 1

HCID 1140Toluene용매

실험 절차

To a solution of 5.0 g of (phenylthio)acetic acid in 20 ml of toluene under nitrogen was added 5.2 ml of oxalyl chloride in four portions. The solution was stirred at room temperature for about twenty hours and then concentrated in vacuo to the oily title compound, which was used in subsequent reactions without further purificaton or characterization.

후처리

  1. concentrationconcentrated in vacuo to the oily title compound, which

출처 및 근거

ORD 기록
ord-9ef97c2bf9824e38b8c136f32ff6aa57
출처 데이터셋
uspto-grants-1987_11
특허 번호
US04704386

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