Azobisisobutyronitrile → Laurylmethacrylate Acrylic Acid

HRID 247564

반응식

HRID 247564 반응식
[CH2:1]([O:13][C:14](=[O:18])[C:15]([CH3:17])=[CH2:16])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[C:19]([OH:23])(=[O:22])[CH:20]=[CH2:21].N(C(C)(CC(C)C)C#N)=NC(C)(CC(C)C)C#N.CC(N=NC(C#N)(C)C)(C#N)C>>[CH2:1]([O:13][C:14](=[O:18])[C:15]([CH3:17])=[CH2:16])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[C:19]([OH:23])(=[O:22])[CH:20]=[CH2:21]

참가 물질

5

반응물 4

HCID 6547AzobisisobutyronitrileHCID 6581Acrylic AcidHCID 8906Lauryl MethacrylateHCID 915372,2'-Azobis(2,4-dimethylvaleronitrile)

생성물 1

HCID 86741893Laurylmethacrylate Acrylic Acid수율 33%

반응 조건

온도
50 °C

실험 절차

To 795.4 g of laurylmethacrylate is added 4.64 g of glacial acrylic acid and 800 g of liquid hydrocarbon sold commercially as Isopar® M by Exxon. Then 0.8 g of 2,2'-azobis(2,4-dimethylvaleronitrile) which is sold commercially as Vazo® 52 by E. I. duPont de Nemours Corporation is added. The solution is agitated, purged with nitrogen for 1 hour and then heated to 50° C. After 12 hours of heating, the temperature of the thickened solution is increased to 60° C. and held there for 2 hours. It is then cooled and mixed with another 800 g of the aforementioned liquid hydrocarbon to give a 33 percent polymer solution.

후처리

  1. additionduPont de Nemours Corporation is added
  2. custompurged with nitrogen for 1 hour
  3. temperatureAfter 12 hours of heating
  4. temperaturethe temperature of the thickened solution is increased to 60° C.
  5. temperatureIt is then cooled
  6. additionmixed with another 800 g of the aforementioned liquid hydrocarbon

출처 및 근거

ORD 기록
ord-3123c02ade5f478e8cb06b0adcc5a922
출처 데이터셋
uspto-grants-1987_11
특허 번호
US04708997

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