1-Decanol → 2-n-Decyloxycarbonylnaphthalene-6-carboxylic acid chloride

HRID 247796

반응식

HRID 247796 반응식
[CH2:1]([OH:11])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10].[CH:12]1[C:21]2[C:16](=[CH:17][C:18]([C:22]([Cl:24])=[O:23])=[CH:19][CH:20]=2)[CH:15]=[CH:14][C:13]=1[C:25](Cl)=[O:26].C(N(CC)CC)C.CN(C1C=CC=CN=1)C>C(Cl)Cl>[CH2:1]([O:11][C:25]([C:13]1[CH:14]=[CH:15][C:16]2[C:21](=[CH:20][CH:19]=[C:18]([C:22]([Cl:24])=[O:23])[CH:17]=2)[CH:12]=1)=[O:26])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10]

참가 물질

6

반응물 4

HCID 81741-DecanolHCID 8471TriethylamineHCID 218852-DimethylaminopyridineHCID 34855962,6-Naphthalenedicarbonyl dichloride

생성물 1

HCID 543160202-n-Decyloxycarbonylnaphthalene-6-carboxylic acid chloride수율 56.3%

시약·촉매·용매 1

HCID 6344Dichloromethane용매

실험 절차

After a solution of n-decyl alcohol (0.5 g), naphthalene-2,6-dicarboxylic acid dichloride (0.6 g), and triethylamine (0.27 g) and a very small amount of dimethylaminopyridine in methylene chloride (50 ml) was stirred at room temperature overnight, the solution was distilled to remove the solvent, until the titled compound (about 0.5 g) was obtained.

후처리

  1. distillationthe solution was distilled
  2. customto remove the solvent

출처 및 근거

ORD 기록
ord-75e52ba2a4e54b1da4dfeb4197a82b67
출처 데이터셋
uspto-grants-1993_05
특허 번호
US05207947

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