Water → HCID 19764388, 화합물

HRID 248146노트

반응식

HRID 248146 반응식
[H-].[Na+].[CH:3]([OH:21])=[CH:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20].[CH2:22](Br)[C:23]1[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=1.O.[CH3:31]N(C)C=O>>[C:23]1([CH2:22][O:21][CH2:3][C:4]([CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20])=[CH2:31])[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=1

참가 물질

6

반응물 5

HCID 962WaterHCID 6228Dimethylformamide2회HCID 7498Benzyl BromideHCID 24758Sodium hydrideHCID 534378461-Octadecen-1-ol

생성물 1

HCID 19764388HCID 19764388, 화합물

실험 절차

To 1.4 g of washed sodium hydride in 100 ml of dry N,N-dimethylformamide is added a solution of 10 g of 1-octadecenol in 100 ml of dimethylformamide followed by 5.8 g of benzyl bromide. This mixture is stirred for 15 hours, then water added and the mixture extracted with ether. The ether extract is dried, evaporated and purified by chromatography, to give 9.0 g of the desired compound.

후처리

  1. extractionthe mixture extracted with ether
  2. extractionThe ether extract
  3. customis dried
  4. customevaporated
  5. custompurified by chromatography

출처 및 근거

ORD 기록
ord-09f473ab93a349b9b56cb68124615b3c
출처 데이터셋
uspto-grants-1993_05
특허 번호
US05208223

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