2-Pyrazoline → Pyrazole

HRID 256291

반응식

HRID 256291 반응식
[NH:1]1[CH2:5][CH2:4][CH:3]=[N:2]1>[Br-].C([N+](CC)(CC)CC)C.C(O)C>[NH:2]1[CH2:3][CH2:4][CH:5]=[N:1]1.[NH:1]1[CH:5]=[CH:4][CH:3]=[N:2]1

참가 물질

5

반응물 1

HCID 669622-Pyrazoline2회

생성물 2

HCID 1048PyrazoleHCID 669622-Pyrazoline

시약·촉매·용매 2

HCID 6285Tetraethylammonium Bromide촉매HCID 702Ethanol용매

실험 절차

234 g of 2-pyrazoline and 64 g of tetraethylammonium bromide were dissolved in 3,000 g of ethanol and electrolyzed with 2 F/mol of 2-pyrazoline at a current density of 6.8 A/dm2 and 30° C. Working up as described in Example 1 gave 18.2 g of 2-pyrazoline and 129 g of pyrazole. This corresponds to a conversion of 92%, a yield of 57% and a selectivity of 62%.

후처리

  1. custom30° C

출처 및 근거

ORD 기록
ord-31d36474095d4c2bb8dc4d9f4c897248
출처 데이터셋
uspto-grants-1987_10
특허 번호
US04702803

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