N-Ethylethylenediamine → HCID 20163758, 화합물

HRID 256336

반응식

HRID 256336 반응식
[C:1]([CH2:3][NH:4][C:5](=[O:21])[C:6]1[CH:11]=[C:10]([Cl:12])[C:9]([NH:13][C:14]([CH3:16])=[O:15])=[CH:8][C:7]=1[O:17]C(=O)C)#[N:2].[CH2:22]([NH:24][CH2:25][CH2:26]N)[CH3:23]>C(=S)=S>[CH2:22]([N:24]1[CH2:25][CH2:26][N:2]=[C:1]1[CH2:3][NH:4][C:5](=[O:21])[C:6]1[CH:11]=[C:10]([Cl:12])[C:9]([NH:13][C:14]([CH3:16])=[O:15])=[CH:8][C:7]=1[OH:17])[CH3:23]

참가 물질

4

반응물 2

HCID 66071N-EthylethylenediamineHCID 54344079N-(Cyanomethyl) 2-acetoxy 4-acetamino 5-chlorobenzamide

생성물 1

HCID 20163758HCID 20163758, 화합물

시약·촉매·용매 1

HCID 6348Carbon Disulfide용매

실험 절차

143 g of N-(cyanomethyl) 2-acetoxy 4-acetamino 5-chlorobenzamide was introduced into a one liter balloon flask provided with sealed agitator, a reflux condenser on which there was disposed a bubble counter containing vaseline oil, a thermometer and a dropping funnel. Thereafter, 123 g of N-ethyl ethylene diamine were rapidly added dropwise. The reaction was exothermic. The temperature rose to 110° C. and the amount of gas evolved was substantial. A thick solution was obtained. The solution was heated to temperature of 120° and then, after 25 minutes of heating, drops of carbon disulphide were added and the temperature was then maintained at 120° for a further period of 20 minutes until the gas ceased to be evolved.

후처리

  1. customprovided
  2. customwith sealed agitator, a reflux condenser on which there
  3. additioncontaining vaseline oil
  4. customrose to 110° C.
  5. customA thick solution was obtained
  6. temperatureThe solution was heated to temperature of 120°
  7. temperatureafter 25 minutes of heating
  8. temperaturethe temperature was then maintained at 120° for a further period of 20 minutes until the gas

출처 및 근거

ORD 기록
ord-d3af57d45db54dd4948e9b937a0ee8dc
출처 데이터셋
uspto-grants-1987_10
특허 번호
US04703055

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