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Acrylamide → Acrylamide 2-Acrylamido-2-Methyl Propyl Sulfonic Acid

HRID 25920
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HRID 25920 반응식
[OH-].[Na+].[C:3]([NH:7][C:8]([CH3:15])([CH3:14])[CH2:9][S:10]([OH:13])(=[O:12])=[O:11])(=[O:6])[CH:4]=[CH2:5].C(N)(=O)C=C.CC(C(OOC(C)(C)C)=O)(C)C>O>[C:3]([NH2:7])(=[O:6])[CH:4]=[CH2:5].[C:3]([NH:7][C:8]([CH3:15])([CH3:14])[CH2:9][S:10]([OH:13])(=[O:11])=[O:12])(=[O:6])[CH:4]=[CH2:5]
참가 물질실험 절차후처리출처 및 근거반응 노트

참가 물질

6

반응물 4

HCID 6579AcrylamideHCID 14798Sodium HydroxideHCID 61238tert-BUTYL PEROXYPIVALATEHCID 653602-Acrylamido-2-methyl-1-propanesulfonic acid

생성물 1

HCID 86735510Acrylamide 2-Acrylamido-2-Methyl Propyl Sulfonic Acid

시약·촉매·용매 1

HCID 962Water용매

실험 절차

Borax (0.6 g.) and 50% aqueous sodium hydroxide (7.2 g.) were dissolved in 52.4 g. of distilled water. 2-acrylamido-2-methyl propyl sulfonic acid (2-AMPSA) (20.4 g.) and acrylamide (AM) (39.4 g.) were dissolved in the caustic solution while maintaining the temperature at <20° C. by cooling. The pH of the final solution was adjusted to 8.0; the solution was then combined with Tween 85 (30.0 g.) and Mentor 28 (50.0 g.). The reaction was conducted according to the procedure of Example 31. 0.5 ml of a 0.01% FAS solution and 0.1 ml of Lupersol 11 was used; polymerization was maintained at <68° C. by cooling. The product was a stable emulsion (5000 cps viscosity).

후처리

  1. temperaturewhile maintaining the temperature at <20° C.
  2. temperatureby cooling
  3. custompolymerization
  4. temperaturewas maintained at <68° C.
  5. temperatureby cooling

출처 및 근거

ORD 기록
ord-bcfc5a81563f4c31a349375bcebb3c0c
출처 데이터셋
uspto-grants-1979_04
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US04147681

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