Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Piperidine → 1-(2-Ethylhexyl)-3-cyano-4,6-dimethylpyrid-2-one
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Piperidine | HCID 8082 | — |
| 반응물 | Acetylacetone | HCID 31261 | — |
| 반응물 | 2-cyano-N-(2-ethylhexyl)acetamide | HCID 4590704 | — |
| 생성물 | 1-(2-Ethylhexyl)-3-cyano-4,6-dimethylpyrid-2-one | HCID 20312180 | 60% |
반응 단계
A mixture of N-(2-ethylhexyl)cyanoacetamide (201.5 g., 1.0 mole), 2,4-pentanedione (100 g., 1.0 mole), piperidine (10 g.) and 2-B-ethanol 300 ml. is refluxed for 24 hours, cooled to room temperature and the solid precipitate is collected by filtration to give 155 g. (60% yield), mp. 84°-89° C. The solid when recrystallized from petroleum ether/benzene has a mp. 89°-90° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04038065 |
| 출처 데이터셋 | uspto-grants-1977_07 |
| ORD ID | ord-eebb1d1a887c465792464673a9ad563e |
| 출처 메모 | uspto-grants-1977_07 |