Dimethyldithiocarbamic acid, dimethylamine → 3,4-Dimethoxy-alpha-(nitromethyl)benzyl dimethyldithiocarbamate

HRID 259461

반응식

HRID 259461 반응식
[CH3:1][O:2][C:3]1[CH:4]=[C:5]([CH:11]=[CH:12][C:13]=1[O:14][CH3:15])[CH:6]=[CH:7][N+:8]([O-:10])=[O:9].[CH3:16][N:17]([CH3:21])[C:18](=[S:20])[S-:19].C[NH2+]C>C(=S)=S>[CH3:16][N:17]([CH3:21])[C:18](=[S:19])[S:20][CH:6]([CH2:7][N+:8]([O-:10])=[O:9])[C:5]1[CH:11]=[CH:12][C:13]([O:14][CH3:15])=[C:3]([O:2][CH3:1])[CH:4]=1

참가 물질

4

반응물 2

HCID 11728Dimethyldithiocarbamic acid, dimethylamineHCID 2220933,4-Dimethoxy-beta-nitrostyrene

생성물 1

HCID 213245963,4-Dimethoxy-alpha-(nitromethyl)benzyl dimethyldithiocarbamate

시약·촉매·용매 1

HCID 6348Carbon Disulfide용매

실험 절차

As in Example 17, reaction of 3,4-dimethoxy-β-nitrostyrene with dimethylammonium dimethyldithiocarbamate in the presence of carbon disulfide gave 3,4-dimethoxy-α-(nitromethyl)benzyl dimethyldithiocarbamate melting at 108° - 110° C. after recrystallization without heating from acetone-methanol solution.

출처 및 근거

ORD 기록
ord-102d64bcdad54a068c0089d8601f147b
출처 데이터셋
uspto-grants-1977_07
특허 번호
US04038288

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