Dimethyldithiocarbamic acid, dimethylamine → 3,4-(Methylenedioxy)-alpha-(nitromethyl)benzyl dimethyldithiocarbamate

HRID 26149

반응식

HRID 26149 반응식
[CH2:1]1[O:14][C:13]2[CH:12]=[CH:11][C:5]([CH:6]=[CH:7][N+:8]([O-:10])=[O:9])=[CH:4][C:3]=2[O:2]1.[CH3:15][N:16]([CH3:20])[C:17](=[S:19])[S-:18].C[NH2+]C>C(=S)=S>[CH3:15][N:16]([CH3:20])[C:17](=[S:18])[S:19][CH:6]([CH2:7][N+:8]([O-:10])=[O:9])[C:5]1[CH:11]=[CH:12][C:13]2[O:14][CH2:1][O:2][C:3]=2[CH:4]=1

참가 물질

4

반응물 2

HCID 11728Dimethyldithiocarbamic acid, dimethylamineHCID 949455-(2-Nitroethenyl)-1,3-benzodioxole

생성물 1

HCID 213246273,4-(Methylenedioxy)-alpha-(nitromethyl)benzyl dimethyldithiocarbamate

시약·촉매·용매 1

HCID 6348Carbon Disulfide용매

실험 절차

As in Example 17, reaction of 3,4-(methylenedioxy)-β-nitrostyrene with dimethylammonium dimethyldithiocarbamate in the presence of carbon disulfide gave 3,4-(methylenedioxy)-α-(nitromethyl)benzyl dimethyldithiocarbamate melting at 122° C.-124° C. when recrystallized without heating from acetone-ethanol solution.

출처 및 근거

ORD 기록
ord-c2556666c56a4f38a98f08ccb528d279
출처 데이터셋
uspto-grants-1979_04
특허 번호
US04148795

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