Stearoyl chloride → 2-Chlorostearoyl chloride

반응식

[C:1]([Cl:20])(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].ClCl.[Cl:23]S(O)(=O)=O.C1C(=C(C#N)C#N)C=CC(=C(C#N)C#N)C=1>>[Cl:23][CH:2]([CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])[C:1]([Cl:20])=[O:19]

참가 물질

반응물 4

HCID 8212Stearoyl chloride

HCID 24526Chlorine

HCID 24638Chlorosulfonic acid

HCID 73697Tetracyanoquinodimethane

생성물 1

HCID 205126172-Chlorostearoyl chloride

실험 절차

Following the procedure of Example I, stearoyl chloride is reacted with chlorine in the presence of ClSO3H and TCNQ. The product is distilled to provide substantially pure 2-chlorostearoyl chloride.

후처리

distillationThe product is distilled

출처 및 근거

ORD 기록: ord-4b0992e459a24daaa1b21148f6ab2d51
출처 데이터셋: uspto-grants-1979_04
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04148811

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