Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
N,N,N',N'-Tetramethylethylenediamine → alpha,alpha-Bis(p-tert.-butylphenyl)-1-vinylimidazole-2-methanol
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | N,N,N',N'-Tetramethylethylenediamine | HCID 8037 | — |
| 반응물 | 1-Vinylimidazole | HCID 66171 | — |
| 반응물 | Bis(4-tert-butylphenyl)methanone | HCID 2758048 | — |
| 반응물 | Butyllithium | HCID 178418339 | — |
| 용매 | Hexane | HCID 8058 | — |
| 생성물 | alpha,alpha-Bis(p-tert.-butylphenyl)-1-vinylimidazole-2-methanol | HCID 12433927 | — |
반응 단계
This compound was prepared by the procedure indicated in Example XXII A, using the following materials: 10 g. (0.03 mol) of 4,4'-di-tert.-butylbenzophenone, 19.5 ml. (0.04 mol) of 20% butyllithium in n-hexane, 3 g. (0.03 mol) of 1-vinylimidazole and 4.9 g. (0.04 mol) of N,N,N', N'-tetramethylethylenediamine. The product was crystallised from ethyl acetate. Melting point 169°-170° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04152441 |
| 출처 데이터셋 | uspto-grants-1979_05 |
| ORD ID | ord-55a25409996f478bbdcc1ae6f54a693a |
| 출처 메모 | uspto-grants-1979_05 |