1-(3-chlorophenyl)-4,5-dihydro-1H-pyrazol-3-amine → 1-(3-chlorophenyl)-1H-pyrazol-3-amine
반응식
[Cl:1][C:2]1[CH:3]=[C:4]([N:8]2[CH2:12][CH2:11][C:10]([NH2:13])=[N:9]2)[CH:5]=[CH:6][CH:7]=1>C(O)C.Cl[Cu]>[Cl:1][C:2]1[CH:3]=[C:4]([N:8]2[CH:12]=[CH:11][C:10]([NH2:13])=[N:9]2)[CH:5]=[CH:6][CH:7]=1참가 물질
4
실험 절차
In the same apparatus and following the same modalities as in Example 1, 5 g (0.0255 mole) of 1-(m-chlorophenyl)-3-amino-2-pyrazoline were suspended in 25 ml of ethanol with addition of 0.2 g of CuCl, under an oxygen head. Oxidation was concluded after about 3 hours. The oxidized product was recovered as in Example 1, obtaining 3.6 g of 1-(m-chlorophenyl)-3-aminopyrazole, melting at 106°-107° C.
후처리
- customThe oxidized product was recovered as in Example 1
출처 및 근거
- ORD 기록
- ord-55082323dc144dcb852e9283355811bf
- 출처 데이터셋
- uspto-grants-1979_04
- 특허 번호
- US04149005
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