Benzoyl chloride → Benzoyl Peroxide

HRID 26630

반응식

HRID 26630 반응식
[C:1](Cl)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[O-:10][O-:11].[Na+].[Na+]>O.C([O-])(=O)CCCCCCCCCCCCCCCCC.[Zn+2].C([O-])(=O)CCCCCCCCCCCCCCCCC>[C:1]([O:10][O:11][C:1](=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

참가 물질

5

반응물 2

HCID 7412Benzoyl chlorideHCID 14803Sodium peroxide

생성물 1

HCID 7187Benzoyl Peroxide

시약·촉매·용매 2

HCID 11178Zinc Stearate촉매HCID 962Water용매2회

실험 절차

One liter of water in a glass vessel of a capacity of 5 liters is cooled to 4° C. with ice. 75 g of Na2O2 are dissolved in water with agitation and cooling. Subsequently, a mixture prepared in advance from 260 g benzoyl chloride and 200 g of a commercially available desensitizing agent on the basis of phthalic ester (Ultramoll TGN, from the firm Bayer A. G., Leverkusen) is added drop by drop to the sodium peroxide solution within 20 minutes. During the first 10 minutes the temperature is held at about 8° C. by means of the addition of ice. During the following 10 minutes ice is added so that the temperature can slowly rise to 15° C. Subsequently, the reaction mixture is for 1/2 hour allowed to continue reacting while being agitated, and 12 g of zinc stearate are stirred into the reaction mixture. The pasty constituents are separated from the excess liquid in a centrifuge with settling sump. After two washing cycles and dehydration by means of a centrifuge one obtains a homogeneous, stable benzoyl peroxide paste with about 50% peroxide, 43% desensitizing agent and a remainder of water and zinc stearate. The paste has a viscosity of 1800 poise.

후처리

  1. temperaturecooling
  2. additionDuring the first 10 minutes the temperature is held at about 8° C. by means of the addition of ice
  3. additionDuring the following 10 minutes ice is added so that the temperature
  4. customcan slowly rise to 15° C
  5. customThe pasty constituents are separated from the excess liquid in a centrifuge

출처 및 근거

ORD 기록
ord-99e0986f28aa46ffb427cbefbcdca25d
출처 데이터셋
uspto-grants-1979_04
특허 번호
US04151106

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