Triethyl phosphonoacetate → HCID 178473138, 화합물

HRID 26653

반응식

HRID 26653 반응식
[CH2:1]([O:3][C:4](=[O:14])[CH2:5][P:6](OCC)([O:8][CH2:9][CH3:10])=[O:7])[CH3:2].P(Cl)(Cl)(Cl)(Cl)[Cl:16].C(OC(=O)CP(OCC)(Cl)=O)C>C1C=CC=CC=1>[CH2:1]([O:3][C:4](=[O:14])[CH2:5][PH:6]([O:8][CH2:9][CH2:10][Cl:16])=[O:7])[CH3:2]

참가 물질

5

반응물 3

HCID 13345Triethyl phosphonoacetateHCID 24819Phosphorus pentachlorideHCID 12634156Ethyl(ethoxychlorophosphinyl)acetate

생성물 1

HCID 178473138HCID 178473138, 화합물

시약·촉매·용매 1

HCID 241Benzene용매

실험 절차

Ethyl(diethoxyphosphinyl)acetate (11.2 gm., 0.05 mol.) and phosphorus pentachloride (10.5 gm., 0.05 mol.) are dissolved in 200 ml. of benzene and refluxed overnight. The solvent is removed in vacuo, leaving yellow, oily, ethyl(ethoxychlorophosphinyl)acetate as residue (11.5 gm.).

후처리

  1. customThe solvent is removed in vacuo
  2. customleaving yellow

출처 및 근거

ORD 기록
ord-f5f7c881caa9453e8959c0b4ff68e9d8
출처 데이터셋
uspto-grants-1979_04
특허 번호
US04151172

연결된 노트

불러오는 중…