반응식
[CH:1]1[C:10]2[C:11]3[CH:20]=[CH:19][C:18]4C(OC(=O)[C:16]5[C:17]=4[C:12]=3[C:13](=[CH:14][CH:15]=5)[C:8]3[C:9]=2[C:4]2[C:5]([C:26](O[C:29](=[O:30])[C:3]=2[CH:2]=1)=[O:27])=[CH:6][CH:7]=3)=O.N1C=CN=C1.[NH2:36][CH:37]([CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH3:49])[CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH3:43].O.C(C1C=CC(C(C)(C)C)=CC=1N1C(=O)C2C3C4C(=CC=2)C2C5C(C=CC=2)=CC=CC=5C=4C=CC=3C1=O)(C)(C)C>O.O.C([O-])(=O)C.[Zn+2].C([O-])(=O)C>[CH2:38]([CH:37]([N:36]1[C:26](=[O:27])[C:5]2[C:4]3[C:9]4[C:8](=[CH:7][CH:6]=2)[C:13]2[C:12]5[C:17]([CH:16]=[CH:15][CH:14]=2)=[CH:18][CH:19]=[CH:20][C:11]=5[C:10]=4[CH:1]=[CH:2][C:3]=3[C:29]1=[O:30])[CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH3:49])[CH2:39][CH2:40][CH2:41][CH2:42][CH3:43]참가 물질
7
실험 절차
1.2 g (3.1 mmol) of perylene-3,4,9, 10-tetracarboxylic dianhydride, 6.2 g of imidazole, 470 mg (2.36 mmol) of 7-aminotridecane (prepared according to J. Prakt. Chem. 1980, 322, 261), 150 mg (0.68 mmol) of zinc acetate dihydrate and 3.0 ml (170 mmol) of water are heated in an autoclave (100 ml) at 190° C. for 24 h. Workup is analogous to that used in the preparation of 2b. Yield 1.25 g (27%).
출처 및 근거
- ORD 기록
- ord-67282756a1ef482bb6fc7c4ab8f27489
- 출처 데이터셋
- uspto-grants-1997_07
- 특허 번호
- US05650513
연결된 노트
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