Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
2,6-Dimethylaniline → N-(1,3-dioxolan-5-ylmethyl)-2,6-dimethylaniline
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 2,6-Dimethylaniline | HCID 6896 | — |
| 반응물 | Potassium Carbonate | HCID 11430 | — |
| 반응물 | 4-(Chloromethyl)-1,3-dioxolane | HCID 240153 | — |
| 촉매 | Tetraethylammonium Chloride | HCID 5946 | — |
| 생성물 | N-(1,3-dioxolan-5-ylmethyl)-2,6-dimethylaniline | HCID 21447788 | — |
반응 단계
2,6-Dimethylaniline (94.5 grams), 5-chloromethyl-1,3-dioxolane (31.8 grams), potassium carbonate (36.7 grams) and tetraethylammonium chloride (2 grams) were charged into a glass reaction vessel equipped with a mechanical stirrer, thermometer and reflux condenser. The reaction mixture was heated at reflux for a period of 48 hours. After this time the mixture was filtered and distilled to yield the desired product N-(1,3-dioxolan-5-ylmethyl)-2,6-dimethylaniline having a boiling point of 132°C under aspirator pressure.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US03946045 |
| 출처 데이터셋 | uspto-grants-1976_03 |
| ORD ID | ord-41eda4bb2c954e3691eb720b45327371 |
| 출처 메모 | uspto-grants-1976_03 |