Boron trifluoride etherate → HCID 178505646, 화합물

HRID 270782

반응식

HRID 270782 반응식
[C:1]([C:3]1[CH:8]=[CH:7][CH:6]=[C:5]([F:9])[CH:4]=1)#[CH:2].[Li]CCCC.[C:15]([C:19](OCC)=O)([F:18])([F:17])[F:16].B(F)(F)F.O(CC)CC.[NH2:33][NH2:34]>C1COCC1.C1C=CC=CC=1>[F:9][C:5]1[CH:4]=[C:3]([C:1]2[NH:34][N:33]=[C:19]([C:15]([F:18])([F:17])[F:16])[CH:2]=2)[CH:8]=[CH:7][CH:6]=1

참가 물질

8

반응물 5

HCID 8000Boron trifluoride etherateHCID 9321HydrazineHCID 9794Ethyl trifluoroacetateHCID 5202181-Ethynyl-3-fluorobenzeneHCID 178418339Butyllithium

생성물 1

HCID 178505646HCID 178505646, 화합물

시약·촉매·용매 2

HCID 241Benzene용매HCID 8028Tetrahydrofuran용매

실험 절차

Following protocol H, 1-Ethynyl-3-fluoro-benzene was treated with n-BuLi, CF3CO2Et and BF3—OEt2 in THF. Reaction with hydrazine in benzene under similar reaction conditions yielded title compound.

후처리

  1. customunder similar reaction conditions

출처 및 근거

ORD 기록
ord-d8bdb191e76f452697277aaab9a78660
출처 데이터셋
uspto-grants-2008_11
특허 번호
US07449576B1

연결된 노트

불러오는 중…