Iodoethane → o-Diethoxybenzene

HRID 275734노트

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HRID 275734 반응식
[CH2:1]([O:3][C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=1[OH:10])[CH3:2].I[CH2:12][CH3:13].C(=O)([O-])[O-].[K+].[K+].C(OCC)(=O)C>CN(C)C=O>[CH2:1]([O:3][C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=1[O:10][CH2:12][CH3:13])[CH3:2]

참가 물질

6

반응물 4

HCID 6340IodoethaneHCID 8857Ethyl AcetateHCID 11430Potassium CarbonateHCID 667552-Ethoxyphenol

생성물 1

HCID 74904o-Diethoxybenzene

시약·촉매·용매 1

HCID 6228Dimethylformamide용매

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온도
80 °C

실험 절차

15.0 g of 2-ethoxyphenol, 18.0 ml of iodoethane and 30.0 g of potassium carbonate were suspended in 150 ml dimethylformamide, and the mixture was stirred at 80° C. for 30 hours. Ethyl acetate was added thereto, and the mixture was washed with water for five times and with brine, and then dried over anhydrous magnesium sulfate. The solvent was evaporated to give the title compound quantitatively as a red-brown oil.

후처리

  1. washthe mixture was washed with water for five times and with brine
  2. dry with materialdried over anhydrous magnesium sulfate
  3. customThe solvent was evaporated

출처 및 근거

ORD 기록
ord-5e127ff570ff4237a3f13c93f6e9d430
출처 데이터셋
uspto-grants-2002_03
특허 번호
US06352989B1

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