Acetone → Benzenamine, 5-chloro-2-(4-chlorophenoxy)-

HRID 27624노트

반응식

HRID 27624 반응식
ClC1C=CC([C:8]2[C:9]([N+:33]([O-])=O)=[C:10]([O:15][C:16]3[CH:21]=[CH:20][C:19]([Cl:22])=[C:18](C4C=CC(Cl)=CC=4)[C:17]=3[N+]([O-])=O)[CH:11]=[CH:12][C:13]=2[Cl:14])=CC=1.CC(C)=O.S(S([O-])=O)([O-])=O.[Na+].[Na+]>O>[Cl:14][C:13]1[CH:12]=[CH:11][C:10]([O:15][C:16]2[CH:21]=[CH:20][C:19]([Cl:22])=[CH:18][CH:17]=2)=[C:9]([CH:8]=1)[NH2:33]

참가 물질

5

반응물 3

HCID 180AcetoneHCID 24489Sodium DithioniteHCID 572553524-Chlorophenyl-4-chloro-2-nitrophenyl ether

생성물 1

HCID 67135Benzenamine, 5-chloro-2-(4-chlorophenoxy)-

시약·촉매·용매 1

HCID 962Water용매

실험 절차

A 140 g. portion of the above nitro derivative in 1400 ml. of acetone is reduced with 560 g. of sodium hydrosulfite in 1400 ml. of water as described in Example 1, giving 5-chloro-2-(p-chlorophenoxy)aniline.

출처 및 근거

ORD 기록
ord-60fa2b14f13f4a0c8c9995497ce85fd2
출처 데이터셋
uspto-grants-1980_09
특허 번호
US04221714

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