1,3-Di(3-methyl-3-hydroxy-1-butynyl)benzene → Mesitylene

HRID 27801노트

반응식

HRID 27801 반응식
[CH3:1]C(O)(C#CC1C=CC=C(Br)C=1)C.CC(O)(C)C#[C:17][C:18]1[CH:23]=[CH:22][CH:21]=[C:20]([C:24]#CC(O)(C)C)[CH:19]=1>>[C:18]1([CH3:17])[CH:19]=[C:20]([CH3:24])[CH:21]=[C:22]([CH3:1])[CH:23]=1

참가 물질

3

반응물 2

HCID 50980371,3-Di(3-methyl-3-hydroxy-1-butynyl)benzeneHCID 23006378HCID 23006378, 화합물

생성물 1

HCID 7947Mesitylene

실험 절차

Referring to Table 1 above, the Conversion ("Conv.") was a weight percent conversion and was calculated by: ##EQU1## Selectivity ("Selec.") in Table 1 means, as appropriate: ##EQU2## The Yield means, as appropriate, the yield of 2-methyl-4-(3-bromophenyl)-3-butyn-2-ol: ##STR15## or 1,3-di(3-methyl-3-hydroxy-1-butynyl)benzene: ##STR16## and was calculated as the product of Conversion times Selectivity. Selectivities and yields were calculated only on isolated crude products by gas chromatography with an appropriate internal standard (mesitylene).

후처리

  1. customSelectivities and yields

출처 및 근거

ORD 기록
ord-ec37ad1be5cf4fbbb5e7f1bbdb274c51
출처 데이터셋
uspto-grants-1980_09
특허 번호
US04223172

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