N-Phenylhydroxylamine → 1-(4-chlorophenyl)-N-phenylmethanimine oxide

HRID 27919

반응식

HRID 27919 반응식
[C:1]1([NH:7][OH:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Cl:9][C:10]1[CH:25]=[CH:24][C:13]([CH:14]=NC2C=CC(Cl)=CC=2C)=[CH:12][CH:11]=1>CCOCC>[Cl:9][C:10]1[CH:25]=[CH:24][C:13]([CH:14]=[N+:7]([C:1]2[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=2)[O-:8])=[CH:12][CH:11]=1

참가 물질

4

반응물 2

HCID 7518N-PhenylhydroxylamineHCID 13017552N-(p-Chlorobenzylidene)-2-methyl-4-chloroaniline

생성물 1

HCID 2545041-(4-chlorophenyl)-N-phenylmethanimine oxide

시약·촉매·용매 1

HCID 3283Diethyl Ether용매2회

실험 절차

N-phenylhydroxylamine (0.052 mole) was dissolved in ether (20 cc). This solution was treated with N-(p-chlorobenzylidene)-2-methyl-4-chloroaniline (13.8 g.) dissolved in ether (50 cc). After 15 min., white crystals had begun to form. Filtration and washing with ether gave α-p-chlorophenyl-N-phenylnitrone.

후처리

  1. customto form
  2. filtrationFiltration
  3. washwashing with ether

출처 및 근거

ORD 기록
ord-0e12529043b64c969cf8dc80bad688c5
출처 데이터셋
uspto-grants-1980_09
특허 번호
US04224340

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