Dimethylformamide → N,N,N,2,2-Pentamethylpropan-1-aminium iodide

반응식

[CH2:1](N)[C:2](C)([CH3:4])[CH3:3].[CH2:7](N(CCCC)CCCC)CCC.C[I:21].[CH3:22][N:23]([CH:25]=O)[CH3:24]>>[I-:21].[CH3:22][N+:23]([CH2:25][C:2]([CH3:4])([CH3:3])[CH3:1])([CH3:7])[CH3:24]

참가 물질

반응물 4

HCID 6228Dimethylformamide

HCID 6328Methyl iodide

HCID 7622Tributylamine

HCID 79882Neopentylamine

생성물 1

HCID 13652289N,N,N,2,2-Pentamethylpropan-1-aminium iodide

실험 절차

11.51 Grams of neopentylamine (Aldrich), 48.7 grams of tributyl amine and 100 ml of DMF were mixed and cooled. 56 Grams of methyl iodide (Aldrich) were added dropwise and the reaction was carried out and worked up as in Example 1.

후처리

temperaturecooled

출처 및 근거

ORD 기록: ord-c51cb8b2898444f0a0cd172d02f82682
출처 데이터셋: uspto-grants-1986_05
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04589977

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