Water → HCID 178418442, 화합물

HRID 2844

반응식

HRID 2844 반응식
[CH2:1]([N:4]([CH2:11][CH2:12][CH3:13])[C:5](=[O:10])[CH2:6][C:7](=[O:9])[CH3:8])[CH2:2][CH3:3].CC(O[Na])=O.O.[Cl-].[C:21]1([N+:27]#[N:28])[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=1>C(O)C>[CH2:11]([N:4]([CH2:1][CH2:2][CH3:3])[C:5](=[O:10])[C:6](=[N:28][NH:27][C:21]1[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=1)[C:7](=[O:9])[CH3:8])[CH2:12][CH3:13]

참가 물질

6

반응물 4

HCID 962WaterHCID 60992Benzenediazonium chlorideHCID 2492073-Oxo-n,n-dipropylbutanamideHCID 178418247HCID 178418247, 화합물

생성물 1

HCID 178418442HCID 178418442, 화합물수율 14.5%

시약·촉매·용매 1

HCID 702Ethanol용매

실험 절차

18.5 g (0.1 mol) of N,N-dipropyl-3-oxobutyramide, 12 g (0.146 mol) of CH3COONa, 20 ml of water, 75 ml of ethanol and a solution of 0.1 mol of phenyldiazonium chloride were treated as described in preparation 2. The precipitated solid was filtered and dried in vacuo yielding 4.2 g of the title compound. M.p.=79°-80° C.

후처리

  1. customas described in preparation 2
  2. filtrationThe precipitated solid was filtered
  3. customdried in vacuo

출처 및 근거

ORD 기록
ord-549c90cb2eaf4302a24586469500c664
출처 데이터셋
uspto-grants-1998_03
특허 번호
US05731322

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