Thiophosgene → HCID 178440816, 화합물
반응식
[C:1]([C:5]1[CH:6]=[C:7]([NH2:11])[CH:8]=[CH:9][CH:10]=1)([CH3:4])([CH3:3])[CH3:2].C(=O)(O)[O-].[Na+].C(Cl)(Cl)=[S:18]>CC(C)=O>[N-:11]=[C:7]=[S:18].[C:1]([C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)([CH3:4])([CH3:3])[CH3:2]참가 물질
5
실험 절차
To 3-(tert-butyl)phenylamine in acetone at 0° C. was added sodium bicarbonate (2 eq) and thiophosgene (2 eq). The mixture was brought to ambient temperature and concentrated and partitioned between ethyl acetate and water. The organic layer was dried with sodium bicarbonate and sodium sulfate and concentrated to yield 3-(tert-butyl)benzenisothiocyanate. MS: MH+=192.
후처리
- customwas brought to ambient temperature
- concentrationconcentrated
- custompartitioned between ethyl acetate and water
- dry with materialThe organic layer was dried with sodium bicarbonate and sodium sulfate
- concentrationconcentrated
출처 및 근거
- ORD 기록
- ord-5c2f9b6dcb724652b0a751510608c005
- 출처 데이터셋
- uspto-grants-2008_09
- 특허 번호
- US07423150B2
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