Dichloromethane → tert-butyl (2S,3S)-3-[tert-butyl(dimethyl)silyl]oxy-2-formyl-piperidine-1-carboxylate

HRID 315570노트

반응식

[C:1]([CH3:2])([CH3:3])([CH3:4])[O:5][C:6](=[O:7])[N:8]1[CH:9]([CH2:22][OH:23])[CH:10]([O:14][Si:15]([CH3:16])([CH3:17])[C:18]([CH3:19])([CH3:20])[CH3:21])[CH2:11][CH2:12][CH2:13]1.[CH3:24][N+:25]1([O-:26])[CH2:27][CH2:28][O:29][CH2:30][CH2:31]1.[CH3:35][CH2:36][CH2:37][CH2:38][CH2:39][CH3:40].[CH3:41][CH2:42][CH2:43][N+:44]([CH2:45][CH2:46][CH3:47])([CH2:48][CH2:49][CH3:50])[CH2:51][CH2:52][CH3:53].[Cl:32][CH2:33][Cl:34].[O:54]=[Ru:55](=[O:56])([O-:57])=[O:58]>>[C:1]([CH3:2])([CH3:3])([CH3:4])[O:5][C:6](=[O:7])[N:8]1[CH:9]([CH:22]=[O:23])[CH:10]([O:14][Si:15]([CH3:16])([CH3:17])[C:18]([CH3:19])([CH3:20])[CH3:21])[CH2:11][CH2:12][CH2:13]1