Silicon carbide → 1-Methoxy-2,7-octadiene

HRID 31564

반응식

HRID 31564 반응식
[C-]#[Si+].[CH3:3][O:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12]>>[CH3:3][O:4][CH2:5][CH:6]=[CH:7][CH2:8][CH2:9][CH2:10][CH:11]=[CH2:12]

참가 물질

3

반응물 2

HCID 9863Silicon carbideHCID 702471-Methoxyoctane

생성물 1

HCID 5350261-Methoxy-2,7-octadiene

실험 절차

Nitrogen gas was introduced downflow to a 1″×18″ 316 s.s. hot tube reactor system containing 67 ml of silicon carbide (SiC) at a total rate of 6.2 ml/min. The hot tube reactor was heated to 450° C. at which time 1-methoxyoctane (MO), obtained from hydrogenation of 1-methoxy-2,7-octadiene, was added downflow at 0.1 ml/min. Under these conditions 1-methoxyoctane was converted to a mixture of 1-octene and mixed internal octenes at 3.3% wt conversion with a selectivity to 1-octene of 10 m % and mixed internal octenes of 90 m %.

후처리

  1. additionNitrogen gas was introduced downflow to a 1″×18″ 316 s

출처 및 근거

ORD 기록
ord-b14c4d5920df40fe8b7b03452914eb2b
출처 데이터셋
uspto-grants-2008_09
특허 번호
US07425658B2

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