Carbon Disulfide → HCID 178505474, 화합물
반응식
[NH2:1][C:2]1[CH:3]=[C:4]([F:9])[CH:5]=[CH:6][C:7]=1[NH2:8].[C:10](=S)=[S:11]>CO>[F:9][C:4]1[CH:5]=[CH:6][C:7]2[NH:8][C:10]([SH:11])=[N:1][C:2]=2[CH:3]=1참가 물질
4
실험 절차
A mixture of 3,4-diamino-1-fluorobenzene (10 g, 79.3 mmol), carbon disulfide (70 ml, 1164 mmol), and methanol (100 ml) was stirred at room temperature for 86 hours and 50 minutes. After the reaction mixture was concentrated, the residue was suspended in hexane. The resultant precipitate was collected by filtration and washed with hexane to obtain the title compound (13.1 g, yield: 98.2%) as a brown solid.
후처리
- concentrationAfter the reaction mixture was concentrated
- filtrationThe resultant precipitate was collected by filtration
- washwashed with hexane
출처 및 근거
- ORD 기록
- ord-31450aeabdf747aeb96b5606f43929aa
- 출처 데이터셋
- uspto-grants-2008_09
- 특허 번호
- US07425634B2
반응 노트
불러오는 중…