Water → N,N-bis[4''-(N-phenyl-1-naphthylamino)-p-terphenyl-4-yl]amine

HRID 31953

반응식

HRID 31953 반응식
[C:1]1([N:7]([C:65]2[C:74]3[C:69](=[CH:70][CH:71]=[CH:72][CH:73]=3)[CH:68]=[CH:67][CH:66]=2)[C:8]2[CH:13]=[CH:12][C:11]([C:14]3[CH:19]=[CH:18][C:17]([C:20]4[CH:25]=[CH:24][C:23]([N:26]([C:30]5[CH:35]=[CH:34][C:33]([C:36]6[CH:41]=[CH:40][C:39]([C:42]7[CH:47]=[CH:46][C:45]([N:48]([C:55]8[C:64]9[C:59](=[CH:60][CH:61]=[CH:62][CH:63]=9)[CH:58]=[CH:57][CH:56]=8)[C:49]8[CH:54]=[CH:53][CH:52]=[CH:51][CH:50]=8)=[CH:44][CH:43]=7)=[CH:38][CH:37]=6)=[CH:32][CH:31]=5)C(=O)C)=[CH:22][CH:21]=4)=[CH:16][CH:15]=3)=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[OH-].[K+].C(C1C=CC=CC=1CC)C.O>CCCCCC>[C:1]1([N:7]([C:65]2[C:74]3[C:69](=[CH:70][CH:71]=[CH:72][CH:73]=3)[CH:68]=[CH:67][CH:66]=2)[C:8]2[CH:13]=[CH:12][C:11]([C:14]3[CH:15]=[CH:16][C:17]([C:20]4[CH:21]=[CH:22][C:23]([NH:26][C:30]5[CH:31]=[CH:32][C:33]([C:36]6[CH:41]=[CH:40][C:39]([C:42]7[CH:47]=[CH:46][C:45]([N:48]([C:55]8[C:64]9[C:59](=[CH:60][CH:61]=[CH:62][CH:63]=9)[CH:58]=[CH:57][CH:56]=8)[C:49]8[CH:54]=[CH:53][CH:52]=[CH:51][CH:50]=8)=[CH:44][CH:43]=7)=[CH:38][CH:37]=6)=[CH:34][CH:35]=5)=[CH:24][CH:25]=4)=[CH:18][CH:19]=3)=[CH:10][CH:9]=2)[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

참가 물질

6

반응물 4

HCID 962WaterHCID 86571,2-DiethylbenzeneHCID 14797Potassium HydroxideHCID 59793205N,N-bis[4''-(N-phenyl-1-naphthylamino)-p-terphenyl-4-yl]acetamide

생성물 1

HCID 59793193N,N-bis[4''-(N-phenyl-1-naphthylamino)-p-terphenyl-4-yl]amine수율 85.5%

시약·촉매·용매 1

HCID 8058Hexane용매

실험 절차

Charged were N,N-bis[4″-(N-phenyl-1-naphthylamino)-p-terphenyl-4-yl]acetamide 82.0 g, a 50% potassium hydroxide aqueous solution 39 g and diethylbenzene 100 ml, and the mixture was heated and refluxed for 3 days. After finishing the reaction, the mixture was left cooling down, and water 100 ml and hexane 500 ml were added thereto. The brown solid matter deposited was filtered off and dried under reduced pressure to obtain 67 g of N,N-bis[4″-(N-phenyl-1-naphthylamino)-p-terphenyl-4-yl]amine.

후처리

  1. additionCharged
  2. temperaturerefluxed for 3 days
  3. customthe reaction
  4. waitthe mixture was left
  5. temperaturecooling down
  6. filtrationThe brown solid matter deposited was filtered off
  7. customdried under reduced pressure

출처 및 근거

ORD 기록
ord-86bb213d299e42d6ac8e1d5218b776b3
출처 데이터셋
uspto-grants-2008_09
특허 번호
US07425654B2

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