Dimethylalumanylium chloride → Dimethyl(pentamethylcyclopentadienyl)aluminum

HRID 321913

반응식

HRID 321913 반응식
[CH3:1][CH:2]1[C:6]([CH3:7])=[C:5]([CH3:8])[C:4]([CH3:9])=[C:3]1[CH3:10].[Li].[Cl-].[CH3:13][Al+:14][CH3:15]>C1(C)C=CC=CC=1>[CH3:13][Al:14]([CH3:15])[C:4]1([CH3:9])[C:3]([CH3:10])=[C:2]([CH3:1])[C:6]([CH3:7])=[C:5]1[CH3:8]

참가 물질

4

반응물 2

HCID 16686359Dimethylalumanylium chlorideHCID 67305831Lithium pentamethylcyclopentadiene

생성물 1

HCID 16708437Dimethyl(pentamethylcyclopentadienyl)aluminum수율 78%

시약·촉매·용매 1

HCID 1140Toluene용매

반응 조건

온도
80 °C

실험 절차

1.14 g of lithium pentamethylcyclopentadiene (C5Me5Li) and 50 ml of toluene were added into a 100-ml Schlenk flask bottle at room temperature. Then 8 ml of dimethylaluminum chloride (1M in hexane) was added to the mixture. The mixture solution was heated at 80° C. for four hours. After the removal of LiCl, the filtrate was vacuum dried to obtain a yellowish dimethyl(pentamethylcyclopentadienyl)aluminum. The yield was 78%.

후처리

  1. customAfter the removal of LiCl
  2. customdried

출처 및 근거

ORD 기록
ord-4e0a52e81c3946bc92d8d6cbb03edb98
출처 데이터셋
uspto-grants-2001_04
특허 번호
US06211106B1

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