Hydrogen Peroxide → Perbenzoic acid

반응식

Cl[C:2]1[CH:7]=[CH:6][CH:5]=[C:4]([C:8]([O:10][OH:11])=[O:9])[CH:3]=1.B([O-])([O-])[O-].[Na+].[Na+].[Na+].FC(F)(F)C(O)=O.C(OC(=O)C)(=O)C.OO>>[CH:3]1[C:4]([C:8]([O:10][OH:11])=[O:9])=[CH:5][CH:6]=[CH:7][CH:2]=1

참가 물질

반응물 5

HCID 784Hydrogen Peroxide

HCID 6422Trifluoroacetic acid

HCID 7918Acetic Anhydride

HCID 70297m-Chloroperbenzoic acid

HCID 159383boric acid, sodium salt

생성물 1

HCID 523077Perbenzoic acid

실험 절차

m-Chloroperbenzoic acid (MCPBA), a mixture of sodium borate and trifluoroacetic acid or a mixture of acetic anhydride and H2O2 is preferably used for the oxidation. If desired, a commercially available wetting agent can additionally be added to the oxidizing agent. The reaction times lie in a wide range and range from about 0.5 to about 15 hours, preferably 1 to 8 hours. The reaction temperature ranges from −20 to about 100° C., preferably from 0 to about 85° C.

후처리

additiona commercially available wetting agent can additionally be added to the oxidizing agent
customThe reaction times
customranges from −20 to about 100° C., preferably from 0 to about 85° C.

출처 및 근거

ORD 기록: ord-cf42e1c3c252406f96f3ed982b503b07
출처 데이터셋: uspto-grants-2001_04
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US06215029B1

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