Trimethoxysilane → HCID 15405388, 화합물

HRID 324167

반응식

HRID 324167 반응식
[O:1]([C:4]1[CH:9]=[CH:8][C:7]([CH2:10][CH:11]=[CH2:12])=[CH:6][CH:5]=1)[C:2]#[N:3].[CH3:13][O:14][SiH:15]([O:18][CH3:19])[O:16][CH3:17]>C1(C)C(C)=CC=CC=1>[O:1]([C:4]1[CH:9]=[CH:8][C:7]([CH2:10][CH2:11][CH2:12][Si:15]([O:18][CH3:19])([O:16][CH3:17])[O:14][CH3:13])=[CH:6][CH:5]=1)[C:2]#[N:3]

참가 물질

4

반응물 2

HCID 17215TrimethoxysilaneHCID 15405387HCID 15405387, 화합물

생성물 1

HCID 15405388HCID 15405388, 화합물수율 42%

시약·촉매·용매 1

HCID 7237O-Xylene용매

실험 절차

To 3.94 g (24.75 mmol) of purified 1-cyanato-4-(2-propenyl)benzene, prepared as described above, at 65° C. was added 10 μL of a 3% solution of Karstedt's™ catalyst (platinum-divinyltetramethyldisiloxane complex) in xylene (United Chemical Technologies, Bristol, Penn.). Trimethoxysilane (Aldrich) was added in 500 μL increments followed by 10 μL increments of the catalyst solution until NMR showed that the reaction was more than 80% complete. The product was distilled twice to yield 2.94 g (42%) of 3-(4-cyanatophenyl)propyltrimethoxysilane. The structure of the product was verified by IR and NMR.

후처리

  1. customat 65° C.
  2. distillationThe product was distilled twice

출처 및 근거

ORD 기록
ord-bb7188265a4d4388926982058a202b5e
출처 데이터셋
uspto-grants-2001_04
특허 번호
US06217943B1

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