Aniline → N-(1-phenylpropan-2-yl)aniline

HRID 325141노트

반응식

HRID 325141 반응식
[NH2:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH3:8][CH:9]=[CH:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1>C(OCC)(=O)C.CCCCCC>[CH3:8][CH:9]([NH:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1)[CH2:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1

참가 물질

4

반응물 2

HCID 6115AnilineHCID 12500beta-Methylstyrene

생성물 1

HCID 418677N-(1-phenylpropan-2-yl)aniline수율 50%

시약·촉매·용매 1

HCID 21226206Ethyl acetate hexane용매

실험 절차

According to GWM, 0.011 mol (=1.00 ml) of aniline and 0.011 mol (=1.43 ml) of β-methylstyrene are reacted with one another. The product is isolated by column chromatography using ethyl acetate/n-hexane (1:10) as eluent, the product (±)-N-(1-methyl-2-phenylethyl)aniline being obtained as a slightly pink liquid.

후처리

  1. customare reacted with one another
  2. customThe product is isolated by column chromatography

출처 및 근거

ORD 기록
ord-420bf818c81e476abec20c16eaf4a5f7
출처 데이터셋
uspto-grants-2001_04
특허 번호
US06222073B1

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