Methane → Zirconocene Bisphenoxide

HRID 325144노트

반응식

HRID 325144 반응식
C[C-:2]1[CH:6]=[CH:5][CH:4]=[CH:3]1.[C-:7]1(C)[CH:11]=[CH:10][CH:9]=[CH:8]1.[Zr+2:13].[C:14]1([OH:20])[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1.C>C1(C)C=CC=CC=1>[O-:20][C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1.[O-:20][C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1.[CH-:2]1[CH:6]=[CH:5][CH:4]=[CH:3]1.[CH-:7]1[CH:11]=[CH:10][CH:9]=[CH:8]1.[Zr+2:13]

참가 물질

5

반응물 3

HCID 297MethaneHCID 996PhenolHCID 129652697Bis(5-methylcyclopenta-1,3-diene);zirconium(2+)

생성물 1

HCID 131722530Zirconocene Bisphenoxide

시약·촉매·용매 1

HCID 1140Toluene용매

실험 절차

In a flask containing 50 ml of toluene, 1.988 millimoles of dimethyl zirconocene were dissolved. Successively under stirring 3.976 millimoles of phenol were added. The solution develops methane according to the reaction:

후처리

  1. dissolutionwere dissolved
  2. additionwere added
  3. customto the reaction

출처 및 근거

ORD 기록
ord-b912e0f94ec540e89a8f139fcd2bdc5f
출처 데이터셋
uspto-grants-2001_04
특허 번호
US06222081B1

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