반응식
C(OOC1(OOC(C)(C)C)CC(C)CC(C)(C)C1)(C)(C)C.[CH2:22]=[CH:23][C:24]1[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=1.[C:30]1(=[O:36])[O:35][C:33](=[O:34])[CH:32]=[CH:31]1>>[CH2:22]=[CH:23][C:24]1[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=1.[C:33]1(=[O:34])[O:35][C:30](=[O:36])[CH:31]=[CH:32]1참가 물질
반응 조건
- 온도
- 100 °C
실험 절차
3.68 g of 1,1-bis(tert-butylperoxy)-3,3,5-trimethylcyclohexane as a polymerization initiator was added to 10 kg of styrene monomer and 0.35 kg of maleic anhydride. The resulting mixture was stirred and then allowed to stand at room temperature overnight, and was filtered through a filter paper to obtain a starting material for polymerization. After replacing with styrene monomer inside an autoclave made of stainless and having a volume of 2 L, the temperature was raised to 100° C and the starting material for polymerization was introduced into the autoclave at a rate of 8 ml/min, and 4 L of a liquid material was distilled from the autoclave. The viscous liquid material distilled after the above liquid material, was introduced to a large amount of hexane to precipitate a styrene-maleic anhydride copolymer resin. After removing the hexane, its composition was analyzed with a 13C-NMR to give the result of styrene/maleic anhydride =99/1 mol %. In addition, the weight average molecular weight measured by a gel permeation chromatography (GPC) gave the result of 200,000.
후처리
- filtrationwas filtered through a filter paper
- customto obtain a starting material
- customfor polymerization
- customthe starting material for polymerization
- distillationwas distilled from the autoclave
- distillationThe viscous liquid material distilled after the above liquid material
- additionwas introduced to a large amount of hexane
- customto precipitate a styrene-maleic anhydride copolymer resin
- customAfter removing the hexane, its composition
- customto give the
출처 및 근거
- ORD 기록
- ord-5247dc3f4b914345969db8506520b324
- 출처 데이터셋
- uspto-grants-1993_12
- 특허 번호
- US05270353
연결된 노트
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