tert-Butanol → HCID 178435351, 화합물

반응식

[CH2:1]([C:3]1[CH:4]=[C:5]2[C:10](=[CH:11][C:12]=1[CH2:13][CH3:14])[C:9](=[O:15])CCC2)[CH3:2].C[C:17]([CH3:20])([O-:19])[CH3:18].[K+].C([OH:26])(C)(C)C>>[CH2:13]([C:12]1[CH:11]=[C:18]2[C:5](=[CH:4][C:3]=1[CH2:1][CH3:2])[C:10](=[O:26])[C:9]([OH:15])=[CH:20][C:17]2=[O:19])[CH3:14]

참가 물질

반응물 3

HCID 6386tert-Butanol

HCID 123663996,7-Diethyl-3,4-dihydronaphthalen-1(2H)-one

HCID 23665647Potassium tert-butoxide

생성물 1

HCID 178435351HCID 178435351, 화합물수율 63%

실험 절차

Autoxidation of 6,7-diethyl-1-tetralone (48g; 0.24 mole ) with potassium t-butoxide in t-butanol as described in example 8(b) afforded 34.60g (63%) of the title compound. Recrystallisation from aqueous ethanol in the presence of charcoal gave a yellow crystalline solid of m.p. 105°-109° C. (Found; C, 70.45; H, 6.10; C14H14O3 1/2H2O requires; C, 70.28; H, 6.32%).

출처 및 근거

ORD 기록: ord-0fe69cb552294af6be42deb9d0acceb6
출처 데이터셋: uspto-grants-1977_04
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04017639

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