Methane → 1,1,1-Triphenyl-4-acetoxy-1-sila-2-butene

HRID 342857

반응식

HRID 342857 반응식
[C:1]([O:4][CH:5]=[CH:6][CH:7]=C)(=[O:3])[CH3:2].[C:9]1([SiH:15]([C:22]2[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=2)[C:16]2[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=2)[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1.C>C1(C)C=CC=CC=1>[C:22]1([Si:15]([C:9]2[CH:10]=[CH:11][CH:12]=[CH:13][CH:14]=2)([C:16]2[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=2)[CH:7]=[CH:6][CH2:5][O:4][C:1](=[O:3])[CH3:2])[CH:23]=[CH:24][CH:25]=[CH:26][CH:27]=1

참가 물질

5

반응물 3

HCID 297MethaneHCID 151951,3-Butadienyl acetateHCID 69922Triphenylsilane

생성물 1

HCID 538005221,1,1-Triphenyl-4-acetoxy-1-sila-2-butene

시약·촉매·용매 1

HCID 1140Toluene용매

실험 절차

A solution of 1-acetoxy-1,3-butadiene (0.1 mol), triphenylsilane (0.1 mol), and Rh2Cl2 (CO)4 (194.5 mg, 0.625 mol) in 100 mL of toluene was stirred at room temperature under argon for 3 days. The reaction mixture is treated with decolorizing charcoal, and the mixture boiled briefly. After cooling, the reaction mixture is filtered through Celite. Concentration of the solution will afford the title compound.

후처리

  1. temperatureAfter cooling
  2. filtrationthe reaction mixture is filtered through Celite

출처 및 근거

ORD 기록
ord-a1c7979ee9ed4078a2a53bd54710432e
출처 데이터셋
uspto-grants-1999_01
특허 번호
US05859232

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