Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Methane → 1,1,1-Triphenyl-4-acetoxy-1-sila-2-butene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Methane | HCID 297 | — |
| 반응물 | 1,3-Butadienyl acetate | HCID 15195 | — |
| 반응물 | Triphenylsilane | HCID 69922 | — |
| 용매 | Toluene | HCID 1140 | — |
| 생성물 | 1,1,1-Triphenyl-4-acetoxy-1-sila-2-butene | HCID 53800522 | — |
반응 단계
A solution of 1-acetoxy-1,3-butadiene (0.1 mol), triphenylsilane (0.1 mol), and Rh2Cl2 (CO)4 (194.5 mg, 0.625 mol) in 100 mL of toluene was stirred at room temperature under argon for 3 days. The reaction mixture is treated with decolorizing charcoal, and the mixture boiled briefly. After cooling, the reaction mixture is filtered through Celite. Concentration of the solution will afford the title compound.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05859232 |
| 출처 데이터셋 | uspto-grants-1999_01 |
| ORD ID | ord-a1c7979ee9ed4078a2a53bd54710432e |
| 출처 메모 | uspto-grants-1999_01 |