Formic Acid → 2,6-Naphthalene dicarboxylic acid copper

반응식

[CH:1]1[C:10]2[C:5](=[CH:6][C:7]([C:11]([OH:13])=[O:12])=[CH:8][CH:9]=2)[CH:4]=[CH:3][C:2]=1[C:14]([OH:16])=[O:15].C(O)=O.[Cu:20].C(O)=O>CO>[Cu:20].[CH:1]1[C:10]2[C:5](=[CH:6][C:7]([C:11]([OH:13])=[O:12])=[CH:8][CH:9]=2)[CH:4]=[CH:3][C:2]=1[C:14]([OH:16])=[O:15]

참가 물질

실험 절차

0.40 g of 2,6-naphthalene dicarboxylic acid was dissolved under heating in a mixture solvent of 4000 cm3 of methanol and 5 cm3 of formic acid. After this solution was cooled to the normal temperature, into this solution under stirring, a further solution in which 3.00 g of formic acid copper was dissolved in 100 cm3 of methanol was dripped and then this was kept still for a few days. Thereafter, the precipitation product was suction-filtered and dried for 110° C./4 hours, whereby 0.35 g of 2,6-naphthalene dicarboxylic acid copper was obtained.