Formic Acid → HCID 69858079, 화합물

HRID 343732

반응식

HRID 343732 반응식
[CH:1]1[C:10]2[C:5](=[CH:6][C:7]([C:11]([OH:13])=[O:12])=[CH:8][CH:9]=2)[CH:4]=[CH:3][C:2]=1[C:14]([OH:16])=[O:15].C(O)=O.[Cu:20].C(O)=O>CO>[Cu:20].[CH:1]1[C:10]2[C:5](=[CH:6][C:7]([C:11]([OH:13])=[O:12])=[CH:8][CH:9]=2)[CH:4]=[CH:3][C:2]=1[C:14]([OH:16])=[O:15]

참가 물질

5

반응물 3

HCID 284Formic AcidHCID 143572,6-Naphthalenedicarboxylic acidHCID 44152240Formic acid, copper salt

생성물 1

HCID 69858079HCID 69858079, 화합물수율 67.6%

시약·촉매·용매 1

HCID 887Methanol용매2회

실험 절차

0.40 g of 2,6-naphthalene dicarboxylic acid was dissolved under heating in a mixture solvent of 4000 cm3 of methanol and 5 cm3 of formic acid. After this solution was cooled to the normal temperature, into this solution under stirring, a further solution in which 3.00 g of formic acid copper was dissolved in 100 cm3 of methanol was dripped and then this was kept still for a few days. Thereafter, the precipitation product was suction-filtered and dried for 110° C./4 hours, whereby 0.35 g of 2,6-naphthalene dicarboxylic acid copper was obtained.

후처리

  1. temperatureAfter this solution was cooled to the normal temperature, into this solution
  2. waitthis was kept still for a few days
  3. filtrationThereafter, the precipitation product was suction-filtered
  4. customdried for 110° C./4 hours

출처 및 근거

ORD 기록
ord-c4bbc6cb1fc74cb0907db7ff81c62b12
출처 데이터셋
uspto-grants-1999_01
특허 번호
US05862796

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