Acenaphthene → Acenaphthylene, dodecahydro-

HRID 34480

반응식

HRID 34480 반응식
[CH2:1]1[C:11]2=[C:12]3[C:7](=[CH:8][CH:9]=[CH:10]2)[CH:6]=[CH:5][CH:4]=[C:3]3[CH2:2]1>[Ni]>[CH2:1]1[CH:11]2[CH:12]3[CH:7]([CH2:8][CH2:9][CH2:10]2)[CH2:6][CH2:5][CH2:4][CH:3]3[CH2:2]1

참가 물질

3

반응물 1

HCID 6734Acenaphthene

생성물 1

HCID 102215Acenaphthylene, dodecahydro-수율 100%

시약·촉매·용매 1

HCID 935Nickel촉매

실험 절차

Acenaphthene was hydrogenated by the same procedure as in Example 1 except that the catalyst was replaced by a Raney nickel catalyst. Perhydroacenaphthene was produced in a yield of 100%, but the yields of Nos. 1 to 4 isomers were 18.9%, 8.3%, 37.4%, and 35.4%, respectively.

출처 및 근거

ORD 기록
ord-4c6ddff5b3c744a1827fabacb7509121
출처 데이터셋
uspto-grants-1988_08
특허 번호
US04761510

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