Furfural → 3,7-Dimethylocta-2,6-Dienal

HRID 344840노트

반응식

HRID 344840 반응식
C(=O)C1OC=CC=1.CC(C)[O-].[Al+3].CC(C)[O-].CC(C)[O-].C([O:23][CH2:24]/[CH:25]=[C:26](/[CH2:28][CH2:29][CH:30]=[C:31]([CH3:33])[CH3:32])\[CH3:27])=O>>[CH3:33][C:31](=[CH:30][CH2:29][CH2:28][C:26](=[CH:25][CH:24]=[O:23])[CH3:27])[CH3:32]

참가 물질

4

반응물 3

HCID 7362FurfuralHCID 11143Aluminum isopropoxideHCID 5282109Geranyl formate

생성물 1

HCID 88433,7-Dimethylocta-2,6-Dienal수율 86%

실험 절차

According to the same procedure of Example 1, using 19.5 g (200 mmol) of furfural, and 642 mg (3 mmol) of aluminum isopropoxide, 18.2 g (100 mmol) of geranyl formate was oxidized to obtain citral at a yield of 86%.

출처 및 근거

ORD 기록
ord-484179483e144d51a31fd703c126bd35
출처 데이터셋
uspto-grants-1991_10
특허 번호
US05053552

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