Hydrochloric Acid → HCID 14233599, 화합물
반응식
[NH2:1][C:2]1[CH:12]=[C:11]([Br:13])[CH:10]=[CH:9][C:3]=1[C:4]([O:6][CH2:7][CH3:8])=[O:5].C(O)C.[ClH:17]>C(OCC)C>[ClH:17].[NH2:1][C:2]1[CH:12]=[C:11]([Br:13])[CH:10]=[CH:9][C:3]=1[C:4]([O:6][CH2:7][CH3:8])=[O:5]참가 물질
5
실험 절차
At room temperature, a solution of 3.09 g (0.0127 mol) of ethyl 2-amino-4-bromobenzoate and 30 ml absolute ethanol was saturated with dry hydrogen chloride gas. A colorless precipitate formed in the warm solution. When it was again at room temperature, the solution was diluted with 30 ml of diethyl ether; the resulting crystalline product was filtered and washed with diethyl ether. Thus there was obtained 2.72 g (77%) of the title compound: m.p. 147°-150° C. Analysis calculated for C9H11BrClNO2 : C, 38.53; H, 3.95; N, 4.99%. Found: C, 38.48; H; 4.02; N, 4.99%.
후처리
- customAt room temperature
- customA colorless precipitate formed in the warm solution
- customwas again at room temperature
- filtrationthe resulting crystalline product was filtered
- washwashed with diethyl ether
출처 및 근거
- ORD 기록
- ord-730f57a68c6848b193f457e602e1c068
- 출처 데이터셋
- uspto-grants-1988_08
- 특허 번호
- US04762838
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