Hexane → 4-Aza-4-cyclohexyl-2-(4-nitrophenyl)-1,6-heptadiene-3,5-dione

HRID 35076

반응식

HRID 35076 반응식
[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([C:10](=[CH2:14])[C:11]([OH:13])=O)=[CH:6][CH:5]=1)([O-:3])=[O:2].[C:15](Cl)(=[O:19])[C:16](Cl)=O.[CH:21]1([NH:27][C:28](=O)[CH:29]=C)[CH2:26][CH2:25][CH2:24]CC1.[CH3:32]CCCCC>>[CH:25]1([CH:24]([C:15](=[O:19])[CH:16]=[CH2:32])[C:11](=[O:13])[C:10]([C:7]2[CH:6]=[CH:5][C:4]([N+:1]([O-:3])=[O:2])=[CH:9][CH:8]=2)=[CH2:14])[CH2:26][CH2:21][NH:27][CH2:28][CH2:29]1

참가 물질

5

반응물 4

HCID 8058HexaneHCID 65578Oxalyl chlorideHCID 137811Acrylamide, N-cyclohexyl-HCID 132780292-(4-Nitrophenyl)prop-2-enoic acid

생성물 1

HCID 200278064-Aza-4-cyclohexyl-2-(4-nitrophenyl)-1,6-heptadiene-3,5-dione

실험 절차

The title compound is prepared analogously to Example 1c starting from 40.5 g of a-(4-nitrophenyl)-acrylic acid, 26.7 g of oxalyl chloride and 26.8 g of N-cyclohexylacrylamide. Melting point 73°-74° (from hexane).

출처 및 근거

ORD 기록
ord-e662789599884e72a40dfc84bcd03121
출처 데이터셋
uspto-grants-1988_08
특허 번호
US04764640

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