Methyl perfluorobutyl ether → Butane, 1-(chloromethoxy)-1,1,2,2,3,3,4,4,4-nonafluoro-

HRID 351480

반응식

HRID 351480 반응식
C(OC)(C(C(C(F)(F)F)(F)F)(F)F)(F)F.[C:16]([O:29][CH2:30][Cl:31])([C:19]([C:22]([C:25]([F:28])([F:27])[F:26])([F:24])[F:23])([F:21])[F:20])([F:18])[F:17].[C:32]([O:45][C:46](Cl)([Cl:48])[Cl:47])([C:35]([C:38]([C:41]([F:44])([F:43])[F:42])([F:40])[F:39])([F:37])[F:36])([F:34])[F:33]>>[C:16]([O:29][CH2:30][Cl:31])([C:19]([C:22]([C:25]([F:28])([F:27])[F:26])([F:24])[F:23])([F:21])[F:20])([F:18])[F:17].[C:32]([O:45][CH:46]([Cl:47])[Cl:48])([C:35]([C:38]([C:41]([F:44])([F:42])[F:43])([F:40])[F:39])([F:37])[F:36])([F:34])[F:33]

참가 물질

5

반응물 3

HCID 164514Methyl perfluorobutyl etherHCID 9925852Butane, 1-(chloromethoxy)-1,1,2,2,3,3,4,4,4-nonafluoro-HCID 131724435HCID 131724435, 화합물

생성물 2

HCID 9925852Butane, 1-(chloromethoxy)-1,1,2,2,3,3,4,4,4-nonafluoro-HCID 9927029C4F9OCHCl2

실험 절차

GLC at the conclusion of the addition showed the following C4F9OCH3(5%), C4F9OCH2Cl (65%) and C4F9OCHCl2 HCl2 (29%) and C4F9OCCl3 (0.2%). The reaction solution was washed first with dilute aqueous potassium hydroxide, and then with water, and distilled using a 40-plate perforated plate column to yield C4F9OCH2Cl, b.p.=87° C. and C4F9OCHCl2, b.p.=96° C. in purifies of about 99%.

후처리

  1. additionGLC at the conclusion of the addition
  2. washThe reaction solution was washed first with dilute aqueous potassium hydroxide
  3. distillationwith water, and distilled

출처 및 근거

ORD 기록
ord-75b885c6c38e4e7893cd358e501abbe0
출처 데이터셋
uspto-grants-2004_06
특허 번호
US06743262B1

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