Sodium ethanethiolate → ethyl 5,7-dihydro-6H-dibenz[c,e]azepine-6-thiocarboximidate

HRID 35158

반응식

HRID 35158 반응식
[CH:1]1[C:11]2[C:10]3[CH:12]=[CH:13][CH:14]=[CH:15][C:9]=3[CH2:8][N:7]([C:16]#[N:17])[CH2:6][C:5]=2[CH:4]=[CH:3][CH:2]=1.[CH2:18]([S-:20])[CH3:19].[Na+]>C(S)C>[CH:1]1[C:11]2[C:10]3[CH:12]=[CH:13][CH:14]=[CH:15][C:9]=3[CH2:8][N:7]([C:16]([S:20][CH2:18][CH3:19])=[NH:17])[CH2:6][C:5]=2[CH:4]=[CH:3][CH:2]=1

참가 물질

4

반응물 2

HCID 4459711Sodium ethanethiolateHCID 198338865,7-dihydro-6H-dibenz[c,e]azepine-6carbonitrile

생성물 1

HCID 20041719ethyl 5,7-dihydro-6H-dibenz[c,e]azepine-6-thiocarboximidate

시약·촉매·용매 1

HCID 6343Ethanethiol용매

실험 절차

starting from 5,7-dihydro-6H-dibenz[c,e]azepine-6-carbonitrile and sodium ethanethiolate in ethanethiol there is obtained ethyl 5,7-dihydro-6H-dibenz[c,e]azepine-6-thiocarboximidate and therefrom with hydrochloric acid in alcohol there is obtained the hydrochloride, m.p. 220° C. (with decomposition);

출처 및 근거

ORD 기록
ord-9b579c6ea71c44829cf397c559a47b98
출처 데이터셋
uspto-grants-1988_08
특허 번호
US04766115

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