(+-)-2-Butanol → 2-butyl 5,7-dihydro-6H-dibenz[c,e]azepine-6-carboximidate

반응식

[CH:1]1[C:11]2[C:10]3[CH:12]=[CH:13][CH:14]=[CH:15][C:9]=3[CH2:8][N:7]([C:16]#[N:17])[CH2:6][C:5]=2[CH:4]=[CH:3][CH:2]=1.[CH3:18][CH:19]([OH:22])[CH2:20][CH3:21]>>[CH:1]1[C:11]2[C:10]3[CH:12]=[CH:13][CH:14]=[CH:15][C:9]=3[CH2:8][N:7]([C:16](=[NH:17])[O:22][CH:19]([CH2:20][CH3:21])[CH3:18])[CH2:6][C:5]=2[CH:4]=[CH:3][CH:2]=1

참가 물질

반응물 2

HCID 6568(+-)-2-Butanol

HCID 198338865,7-dihydro-6H-dibenz[c,e]azepine-6carbonitrile

생성물 1

HCID 200417212-butyl 5,7-dihydro-6H-dibenz[c,e]azepine-6-carboximidate

실험 절차

starting from 5,7-dihydro-6H-dibenz[c,e]azepine-6-carbonitrile and 2-butanol there is obtained 2-butyl 5,7-dihydro-6H-dibenz[c,e]azepine-6-carboximidate as a resinous product, 1H-NMR(CDCl3): 1.02 (t, CH2CH3), 1.35 (d, CH--CH3), 1.4-2.0 (m, 2H), 4.23 (s, 4H), 4.83 (m, 1H), 7.3-7.7 (8H);

출처 및 근거

ORD 기록: ord-ea00ba65867849b59ddc89beb0e3ca9d
출처 데이터셋: uspto-grants-1988_08
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04766115

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