Sodium Carbonate → HCID 15612244, 화합물

HRID 35194

반응식

HRID 35194 반응식
[N:1]1[CH:6]=[CH:5][CH:4]=[C:3]([CH2:7][C:8]2[CH:17]=[CH:16][C:15]3[C:10](=[CH:11][CH:12]=[C:13]([C:18]4([CH3:23])OCC[O:19]4)[CH:14]=3)[CH:9]=2)[CH:2]=1.C(=O)([O-])[O-].[Na+].[Na+]>Cl>[N:1]1[CH:6]=[CH:5][CH:4]=[C:3]([CH2:7][C:8]2[CH:17]=[CH:16][C:15]3[C:10](=[CH:11][CH:12]=[C:13]([C:18](=[O:19])[CH3:23])[CH:14]=3)[CH:9]=2)[CH:2]=1

참가 물질

4

반응물 2

HCID 10340Sodium CarbonateHCID 156122432-(3-Pyridylmethyl)-6-(2-methyl-1,3-dioxolan-2-yl)naphthalene

생성물 1

HCID 15612244HCID 15612244, 화합물수율 101.3%

시약·촉매·용매 1

HCID 313Hydrochloric Acid용매

실험 절차

A solution of 150 mg of 2-(3-pyridylmethyl)-6-(2-methyl-1,3-dioxolan-2-yl)naphthalene in 15 ml of 1N hydrochloric acid was allowed to stand for 3 hours at room temperature. The solution was neutralized with sodium carbonate and extracted with methylene chloride. The organic layer was dried over sodium sulfate and the solvent removed under reduced pressure to give 130 mg of 2-(3-pyridylmethyl)-6-acetylnaphthalene as an oil.

후처리

  1. extractionextracted with methylene chloride
  2. dry with materialThe organic layer was dried over sodium sulfate
  3. customthe solvent removed under reduced pressure

출처 및 근거

ORD 기록
ord-d087129627ad4ec4a8be14aecff590ba
출처 데이터셋
uspto-grants-1988_08
특허 번호
US04766127

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