Potassium Carbonate → Bis(di-p-tolylamino)benzo[a]perylene

HRID 353413노트

반응식

HRID 353413 반응식
[C:1]1([CH3:15])[CH:6]=[CH:5][C:4]([NH:7][C:8]2[CH:13]=[CH:12][C:11]([CH3:14])=[CH:10][CH:9]=2)=[CH:3][CH:2]=1.C(=O)([O-])[O-].[K+].[K+].Br[C:23]1[CH:24]=[C:25]2[C:42]3[C:39]([C:40]=1Br)=[CH:38][CH:37]=[CH:36][C:35]=3[C:34]1[C:43]3[C:30]([CH:31]=[C:32]4[CH:47]=[CH:46][CH:45]=[CH:44][C:33]4=1)=[CH:29][CH:28]=[CH:27][C:26]2=3>O.[Cu]>[C:11]1([CH3:14])[CH:12]=[CH:13][C:8]([N:7]([C:23]2[CH:24]=[C:25]3[C:42]4[C:39]([C:40]=2[N:7]([C:8]2[CH:9]=[CH:10][C:11]([CH3:14])=[CH:12][CH:13]=2)[C:4]2[CH:3]=[CH:2][C:1]([CH3:15])=[CH:6][CH:5]=2)=[CH:38][CH:37]=[CH:36][C:35]=4[C:34]2[C:43]4[C:30]([CH:31]=[C:32]5[CH:47]=[CH:46][CH:45]=[CH:44][C:33]5=2)=[CH:29][CH:28]=[CH:27][C:26]3=4)[C:4]2[CH:3]=[CH:2][C:1]([CH3:15])=[CH:6][CH:5]=2)=[CH:9][CH:10]=1

참가 물질

6

반응물 3

HCID 11430Potassium CarbonateHCID 69293Benzenamine, 4-methyl-N-(4-methylphenyl)-HCID 21910019Dibromobenzo[a]perylene

생성물 1

HCID 21910029Bis(di-p-tolylamino)benzo[a]perylene

시약·촉매·용매 2

HCID 23978Copper촉매HCID 962Water용매

실험 절차

Then, two equivalents of di-p-tolylamine, potassium carbonate, and copper power were added to the thus obtained dibromobenzo[a]perylene. This mixture stood still for reaction at 200 degrees centigrade for thirty hours. After reactant solution was diluted with water, reactant was extracted by chloroform. Thereafter, the reactant was refined in a conventional manner to thereby obtain bis(di-p-tolylamino)benzo[a]perylene.

후처리

  1. customThis mixture stood still for reaction at 200 degrees centigrade for thirty hours
  2. extractionwas extracted by chloroform

출처 및 근거

ORD 기록
ord-65e4863b74a84f75b8f25ed37ec71346
출처 데이터셋
uspto-grants-2004_06
특허 번호
US06753097B2

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